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Gannett, Cara N.; Peterson, Brian M.; Melecio-Zambrano, Luis; Trainor, Colleen Q.; Fors, Brett P.; Abruña, Héctor D. (, Journal of Materials Chemistry A)null (Ed.)The increasing demands for high-power electrical energy storage technologies require the development of new electrode materials and architectures with fast ion and electron transport. Herein, we report a new family of ter-polymers as battery cathode materials which exhibit significantly improved performance over their parent co-polymers: poly(phenylene-phenazine), and poly(1,3,5-phenylene-phenazine). The high electronic conductivity of poly(phenylene-phenazine) and fast ionic transport of poly(1,3,5-phenylene-phenazine) are combined in this series of ter-polymers, exhibiting improved battery performances which are especially apparent at high rates. The optimized ter-polymer delivers 180 mA h g −1 when discharged at 16 A g −1 , demonstrating the effectiveness of balancing ionic and electronic transport properties.more » « less
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Gannett, Cara N.; Melecio-Zambrano, Luis; Theibault, Monica Jo; Peterson, Brian M.; Fors, Brett P.; Abruña, Héctor D. (, Materials Reports: Energy)null (Ed.)
